all 12 Chem Organics Flashcards

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created 3 months ago by emilygilm
updated 3 months ago by emilygilm
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1

alkane

c-c

2

alkene

c=c

3

alkyne

c=c

4

amine

C-NH2

5

caboxcylic acid

C-COOH

C= O -OH

6

carboxylic salt ends in

ate

7

geometric isomer

2 different groups attached to each c in the c=c

8

why must geometric isomer have c=c

c=c has no free rotation about it - fixed

9

what single reaction can alkanes do

substitution - no c=c to break

10

alkene -> haloalkane

reagents/ conditions

HBr

HCl

11

Alkene -> alcohol

reagents/ conditions

H2O/H+

12

alkene -> polymer

reagents/ conditions

c=c broken

13

alkene -> diol

reagents/ conditions

MnO4 -

(purple -> brown solid)

14

alkene -> dihaloalkane

reagents/ conditions

Br2

orange -> colourless FAST

15

alkene -> alkane

reagents/ conditions

H2/Pt orr Ni

with heat

unsaturated -> saturated

16

alkyne -> alkene

reagents/ conditions

H2/Pt orr Ni

with heat

17

alkene -> haloalkane

reaction type

addition

18

Alkene -> alcohol

reaction type

addition

19

alkene -> polymer

reaction type

addition

20

alkene -> diol

reaction type

addition

21

alkene -> dihaloalkane

reaction type

addition

22

alkene -> alkane

reaction type

addition

23

alkyne -> alkene

reaction type

addition

24

alkane -> haloalkane

reagents/ conditions

Br2

UV

orange to colourless SLOW (10 mins)

+HBr/HCl as biproduct

25

alkene -> alkane

reaction type

substitution

26

alcohol -> haloalkane

reagents/ conditions

PCl5/PCl3/SOCl2

27

alcohol -> haloalkane

reaction type

substitution

28

haloalkane -> alcohol

reaction type

sub

29

haloalkane -> alcohol

reagents/ conditions

KOH (aq)

30

haloalkane -> amine

reagents/ conditions

NH3 (alc) conc

31

haloalkane -> amine

reaction type

sub

32

alcohol -> alkene

reagents/ conditions

H2SO4 conc

heat

33

alcohol -> alkene

reaction type

elimination

34

haloalkane -> alkene

reaction type

elimination

35

haloalkane -> alkene

reagents/ conditions

KOH (alc)

heat

36

amine -> ammonium salt

reaction type

acid/base

37

amine -> ammonium salt

reagents/ conditions

HCl/H2SO4/HNO3

38

carboxylic acid -> carboxylic salt

reaction type

acid/base

39

carboxylic acid -> carboxylic salt

reagents/ conditions

NaOH/NaHCO2/Na2CO3

(CO2 biproduct if carbonate)

40

alcohol -> carboxylic acid

reagents/ conditions

ONLY PRIMARY (1o) ALCOHOLS

acidified MnO4 -/H+

purple to colourless

OR

Cr2O7 2-

orange to green

41

alcohol -> carboxylic acid

reaction type

oxidation

42

Soluble compounds

Amines

Carboxylic acids

Alcohols

43

Insoluble compounds

Alkanes

Haloalkanes

Alkenes

Alkynes

44

polymers at room temp

solid

45

monomers at room temp

gas/liquid

46

polymer: strong c-c covalent bonds meeaan

most) are unreactive and resistant.

saturated

47

polymer high molar mass means

high mp and bp

48

monomer low molar mass means

low mp and bp

49

monomer weak c=c bonds mean

reactive and unresistant

unsaturated