reactions 12 Chem Organics Flashcards

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created 3 months ago by emilygilm
updated 3 months ago by emilygilm
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1

alkane

c-c

2

alkene

c=c

3

alkyne

c=c

4

amine

C-NH2

5

caboxcylic acid

C-COOH

C= O -OH

6

carboxylic salt ends in

ate

7

geometric isomer

2 different groups attached to each c in the c=c

8

why must geometric isomer have c=c

c=c has no free rotation about it - fixed

9

what single reaction can alkanes do

substitution - no c=c to break

10

alkene -> haloalkane

reagents/ conditions

HBr

HCl

11

Alkene -> alcohol

reagents/ conditions

H2O/H+

12

alkene -> polymer

reagents/ conditions

c=c broken

13

alkene -> diol

reagents/ conditions

MnO4 -

(purple -> brown solid)

14

alkene -> dihaloalkane

reagents/ conditions

Br2

orange -> colourless FAST

15

alkene -> alkane

reagents/ conditions

H2/Pt orr Ni

with heat

unsaturated -> saturated

16

alkyne -> alkene

reagents/ conditions

H2/Pt orr Ni

with heat

17

alkene -> haloalkane

reaction type

addition

18

Alkene -> alcohol

reaction type

addition

19

alkene -> polymer

reaction type

addition

20

alkene -> diol

reaction type

addition

21

alkene -> dihaloalkane

reaction type

addition

22

alkene -> alkane

reaction type

addition

23

alkyne -> alkene

reaction type

addition

24

alkane -> haloalkane

reagents/ conditions

Br2

UV

orange to colourless SLOW (10 mins)

+HBr/HCl as biproduct

25

alkene -> alkane

reaction type

substitution

26

alcohol -> haloalkane

reagents/ conditions

PCl5/PCl3/SOCl2

27

alcohol -> haloalkane

reaction type

substitution

28

haloalkane -> alcohol

reaction type

sub

29

haloalkane -> alcohol

reagents/ conditions

KOH (aq)

30

haloalkane -> amine

reagents/ conditions

NH3 (alc) conc

31

haloalkane -> amine

reaction type

sub

32

alcohol -> alkene

reagents/ conditions

H2SO4 conc

heat

33

alcohol -> alkene

reaction type

elimination

34

haloalkane -> alkene

reaction type

elimination

35

haloalkane -> alkene

reagents/ conditions

KOH (alc)

heat

36

amine -> ammonium salt

reaction type

acid/base

37

amine -> ammonium salt

reagents/ conditions

HCl/H2SO4/HNO3

38

carboxylic acid -> carboxylic salt

reaction type

acid/base

39

carboxylic acid -> carboxylic salt

reagents/ conditions

NaOH/NaHCO2/Na2CO3

(CO2 biproduct if carbonate)

40

alcohol -> carboxylic acid

reagents/ conditions

ONLY PRIMARY (1o) ALCOHOLS

acidified MnO4 -/H+

purple to colourless

OR

Cr2O7 2-

orange to green

41

alcohol -> carboxylic acid

reaction type

oxidation