OChem 2 Explanations Flashcards


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created 3 months ago by ashliechellsie
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1

Why is Cl2 non-selective?

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2

Why is Br2 selective?

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3

Design an exp to determine if a rxn occurs via radicals not ionic (SN1, SN2, etc).

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4

What is the order of importance in which structures contribute to the hybrid

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5

What is resonance?

e- delocalization through conjugated systems (need p orbitals)

6

Why is the length of the C-C for conjugated dienes unusually short? (2 arguments)

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7

Completely conjugated →___ λmax ∴ absorbs ___ wavelength (UV light)

high; greater

8

Why is the kinetic product faster than the thermodynamic product?

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9

For Diels Alder rxns, why does the diene have to be in s-cis conformation?

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10
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Draw MOs & Frost Circle for the benzene.

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11
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Draw MOs for 1,3 - butadiene.

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12
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Draw Frost Circle

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13

Why is breaking Ar the RDS?

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14

ELECTRONIC ARGUMENT

Why is methyl an o/p director?

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15

Why is NO2 a meta director?

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