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Orgo 2 Ch 18 Regents

1.

Formation of Cyanohydrin From ketones/Aldehydes

Product: OH/CN

2.

Hydrate/ Gem-doil formation from aldehydes/ketones

Product: 2 OH

Reagent: H2O

3.

Reaction between aldehydes/ketones and HX

Product: HX and OH (x = F, Br, I, Cl)

Regeant: HX

4.

Grignard Regeant Reaction between Aldehydes/ketones

Product: OH

Reagent: RMgX/H3O

5.

Organolithium Reagent Reaction between Aldehydes/ketones

Product: OH

Reagent:

6.

Reduction of Aldehydes

Product: OH

Reagent: LiAlH4/H3O+

7.

Reduction of Aldehydes

Product: OH

Reagent: NaBH4/ EtOH

8.

Reduction of Ketones

Product: OH

Reagent: NaBH4/ EtOH &

9.

Reduction of Ketones

Product: OH

Reagent: LiAlH4/H3O+

10.

Aldehyde/Ketone Reduction using NADH & enzyme catalysts

Product: OH

Reagent: NADH/enzyme

11.

Clemmensen reduction

Product: More H

Reagent: Zn(Hg)/ HCL

12.

Oxidation of aldehydes to COOH(carboxylic acids)

Product: COOH

Reagent: (KMnO4, OH-/ H3O+) + more-->

13.

Baeyer Villiger reaction: Ketone to esters

Product: esters

Reagent: CF3Co3H

14.

Baeyer Villiger reaction: Aldehydes to Carboxylic acids

Product: COOH

Reagent: CF3CO3H