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RJ Dillon: Disinfection

1.

Chlorine is how many times heavier than air?

2.5

2.

A quart of liquid chlorine will evaporate into how many quarts of gaseous chlorine?

450

3.

At what temperature does a fusible plug melt?

Between 158° and 165°F.

4.

How many fusible plugs are there on a ton cylinder?

6

5.

How many fusible plugs are there on a 100 or 150 pound chlorine cylinder?

1

6.

What is the most common cause of a chlorine leak?

Lead washer failure or failure to change lead washer

7.

What type of respirator is needed when entering a chlorine room?

SCBA

8.

What is the IDLH for chlorine?

10

9.

How many ppm of chlorine in a room will bring death in seconds?

1,000 ppm or 0.10% by volume

10.

What percentage of the air is oxygen?

20.9%

11.

What chemical is used to oxidize iron from water?

Chlorine

12.

How do you open a chlorine cylinder?

With a six inch box wrench

13.

The iodometric test is used to test for what parameter?

Ozone Residual

14.

What is the minimum free chlorine residual for the distribution system?

0.2 mg/L

15.

What is the minimum combined residual?

0.6 mg/L

16.

What is the maximum residual disinfectant level?

4 mg/L

17.

What does the C in CT value mean?

Concentration of the chlorine residual

18.

What is measured from the chlorine application point to the point where the chlorine residual is taken?

Time

19.

What does the T mean in CT value?

Time

20.

How many pounds of chlorine can you withdraw from a ton cylinder in a day?

400 pounds

21.

How many pounds of chlorine can you draw from a 100 or 150 pound cylinder in a day?

40 pounds

22.

When chlorine is used to disinfect drinking water, the chlorine cylinders are placed on what device to measure usage?

Scale

23.

What is a device used to measure the flow rate of liquid or gasses?

Rotameter

24.

The chlorine scale reading does not equal the rotameter setting for the pass 24 hours. What is the most likely cause?

Air leak down stream of the chlorinator

25.

Pumping dry air into a container or cylinder to assist with the withdrawal of a liquid or gas is called?

Air padding

26.

What is an open or vertical drop or space that separates a potable drinking water supply from an unapproved water or nonpotable water called?

Air gap

27.

What is the most common cause of water borne illnesses in the US?

Cross-connection

28.

What method is considered the most reliable in measuring chlorine residuals?

Amperometric Titration

29.

The addition of chlorine until the demand is satisfied and, thereafter, every drop of chlorine added is free residual is called?

Breakpoint chlorination

30.

What is the disadvantage of breakpoint chlorination?

THM formation

31.

Substances which cause cancer are called?

Carcinogens

32.

What do you call a substance that changes the speed or yield of a chemical reaction without being consumed or chemically changed?

A catalyst

33.

What parameter is determined by this formula? Cl₂ dosage- Residual -?

Demand

34.

What do you call the indicator organism that is found in the intestines of warm blooded animals, including human beings, and in plants, soil, water, and air?

Coliform

35.

What is DPD used for?

Measuring chlorine residuals

36.

Why is chlorine added to drinking water?

To disinfect the water

37.

How many pounds of chlorine can you withdraw from a cylinder in 24 hours?

38.

Disease causing organisms are called?

Pathogens

39.

What does HTH mean?

High Test Hypochlorite

40.

What does OCI mean?

Hypochlorite

41.

What does HOCl mean?

Hypochlorous Acid

42.

What is NaOCI?

Sodium Hypochlorite (bleach)

43.

An increase in the heterotrophic plate count indicates?

Nitrification

44.

What do the initials MPN mean?

Most Probable Number

45.

What bacteria break down ammonia nitrogen to nitrites?

Nitrosomonas

46.

Which bacteria break down nitrites to nitrates?

Nitrobacter

47.

Which are the ideal conditions for nitrification to take place?

A dark environment, temperature between 25-30°C, a pH of 7.5-8.5, and free ammonia available

48.

What is used to detect a chlorine leak?

Ammonia

49.

What is used to detect a sulfur dioxide leak?

Ammonia

50.

What is used to detect an ammonia leak?

Hydrochloric acid

51.

If your plant is pre-chlorinating and you find that you are exceeding the MCL for THMS, what should you do?

Stop pre-chlorinating

52.

Naturally occurring volatile organic compounds react with chlorine and form what cancer causing compound?

THMS

53.

A pure chemical substance that is used to make new products or is used in chemical tests to measure, detect, or analyze other substances is called?

A reagent

54.

The concentration of chlorine present in water after the chlorine demand has been satisfied is called?

Residual

55.

What is this formula used to detect? Demand + Residual =?

Dosage

56.

The Dosage is 5 ppm and the residual is 3 ppm. What is the demand?

2 ppm

57.

What do you call the process of adding a chemical reagent in small increments until completion of a reaction, as signaled by the end point?

Titration

58.

What do you call the cloudy appearance of water caused by the presence of suspended and colloidal matter?

Turbidity

59.

Why are water plant operators concerned with turbidity?

Turbidity interferes with disinfection

60.

What is the MCL for turbidity?

0.5 Nephelometric units

61.

Name four bacteria found in contaminated water?

Typhoid, Cholera, Dysentery, and Salmonella

62.

Name two parasites that are found in contaminated water?

Cryptosporidium and Giardia lamblia

63.

What determines the number of coliform samples that a water system has to take?

Population served

64.

What is the MCL for coliform?

65.

If a sample tests positive for coliform what actions should be taken?

Retest at the site within 24 hour notification of the positive test and sample one site upstream and downstream from the positive site.

66.

If a water system samples 40 or more sites for coliform, how many positive samples are allowed?

2 or 5%

67.

If a water system samples 39 or fewer sites for coliform, how many positive samples are allowed?

1

68.

What are the optimum conditions for disinfection?

High Cl2 concentration, long contact time, low pH, and low turbidity

69.

Why is turbidity of the water important?

High turbidity interferes with disinfection and coagulation

70.

The Surface Water Treatment Rule (SWTR) requires what minimum level of water treatment?

Disinfection and Filtration

71.

Besides chlorination and ammoniation, what other processes reduce pathogens in the water?

Coagulation, Filtration, and Sedimentation

72.

Ultraviolet rays are used to disinfect water. What limits the UV rays efficiency?

No residual; also, if a pathogen is caught between two particles, the rays have no effect on the pathogen.

73.

What color is chlorine gas?

Greenish-yellow

74.

Chlorine cylinders are filled to what capacity?

85% to allow for the expansion of the liquid into the gaseous state

75.

How many parts per million of chlorine is needed to oxidize one ppm of H2S to elemental sulfur?

2.08 mg/L

76.

How many parts per million of chlorine is needed to oxidize one ppm of H₂S to sulfates?

8.32 mg/L

77.

If sulfur dioxide comes into contact with a person's mucous membrane, what can happen?

The formation of sulfuric acid (H₂SO₄)

78.

What does this chemical reaction indicate?

Oxidation of H₂S by chlorine to elemental sulfur

79.

What does this chemical reaction indicate?

Oxidation of H₂S by chlorine to sulfates or sulfuric acid (H₂SO₄)

80.

In the last 4 questions, what do you call the oxidation process that took place?

Sub-residual chlorination

81.

In the normal pH range of drinking water, what is the usual form of chlorine?

Monochloramines

82.

When you add ammonia to chlorine you form?

Chloramines

83.

When chlorine is added to water what is the usual first reaction?

Chlorine is used up (destroyed) by reducing compounds (viruses, bacteria, solids, parasites, etc)

84.

After the reduction of the chlorine dosage, what reaction takes place?

Chlororganics and chloramines are formed - residual is present

85.

What is the next reaction in the chlorination chain?

Residual is reduced-chlororganics and chloramines destroyed

86.

After the reaction in question 85, what takes place?

Question 85:

What is the next reaction in the chlorination chain?

Breakpoint chlorination

87.

What causes the swimming pool taste and odor in water?

Low chlorine residual - plant did not use breakpoint chlorination

88.

What is the best residual for disinfection?

Free available chlorine

89.

At water pH levels of 4.0 or lower, what form will chlorine take?

Trichloramine

90.

Above pH of 7.5 chlorine is found as?

Monochloramines

91.

Dichloramines and monochloramines exist together at what pH range?

5.5-7.5

92.

Dichloramines and trichloramines are associated with what water complaint?

Tastes and odors

93.

If chlorine is used to treat an odor caused by phenols (benzene), what happens?

The odor and taste are intensified

94.

Customers are complaining of a sweet, aromatic, medicinal taste in the water. What is the likely cause?

Phenols

95.

What is the best method to remove tastes and odors caused by phenols?

GAC

96.

To avoid THM formation, what options are available to the WTP?

Switch disinfectants, remove the precursors, or form THMs and remove them after they are formed.