RJ Dillon: Disinfection
Chlorine is how many times heavier than air?
2.5
A quart of liquid chlorine will evaporate into how many quarts of gaseous chlorine?
450
At what temperature does a fusible plug melt?
Between 158° and 165°F.
How many fusible plugs are there on a ton cylinder?
6
How many fusible plugs are there on a 100 or 150 pound chlorine cylinder?
1
What is the most common cause of a chlorine leak?
Lead washer failure or failure to change lead washer
What type of respirator is needed when entering a chlorine room?
SCBA
What is the IDLH for chlorine?
10
How many ppm of chlorine in a room will bring death in seconds?
1,000 ppm or 0.10% by volume
What percentage of the air is oxygen?
20.9%
What chemical is used to oxidize iron from water?
Chlorine
How do you open a chlorine cylinder?
With a six inch box wrench
The iodometric test is used to test for what parameter?
Ozone Residual
What is the minimum free chlorine residual for the distribution system?
0.2 mg/L
What is the minimum combined residual?
0.6 mg/L
What is the maximum residual disinfectant level?
4 mg/L
What does the C in CT value mean?
Concentration of the chlorine residual
What is measured from the chlorine application point to the point where the chlorine residual is taken?
Time
What does the T mean in CT value?
Time
How many pounds of chlorine can you withdraw from a ton cylinder in a day?
400 pounds
How many pounds of chlorine can you draw from a 100 or 150 pound cylinder in a day?
40 pounds
When chlorine is used to disinfect drinking water, the chlorine cylinders are placed on what device to measure usage?
Scale
What is a device used to measure the flow rate of liquid or gasses?
Rotameter
The chlorine scale reading does not equal the rotameter setting for the pass 24 hours. What is the most likely cause?
Air leak down stream of the chlorinator
Pumping dry air into a container or cylinder to assist with the withdrawal of a liquid or gas is called?
Air padding
What is an open or vertical drop or space that separates a potable drinking water supply from an unapproved water or nonpotable water called?
Air gap
What is the most common cause of water borne illnesses in the US?
Cross-connection
What method is considered the most reliable in measuring chlorine residuals?
Amperometric Titration
The addition of chlorine until the demand is satisfied and, thereafter, every drop of chlorine added is free residual is called?
Breakpoint chlorination
What is the disadvantage of breakpoint chlorination?
THM formation
Substances which cause cancer are called?
Carcinogens
What do you call a substance that changes the speed or yield of a chemical reaction without being consumed or chemically changed?
A catalyst
What parameter is determined by this formula? Cl₂ dosage- Residual -?
Demand
What do you call the indicator organism that is found in the intestines of warm blooded animals, including human beings, and in plants, soil, water, and air?
Coliform
What is DPD used for?
Measuring chlorine residuals
Why is chlorine added to drinking water?
To disinfect the water
How many pounds of chlorine can you withdraw from a cylinder in 24 hours?

Disease causing organisms are called?
Pathogens
What does HTH mean?
High Test Hypochlorite
What does OCI mean?
Hypochlorite
What does HOCl mean?
Hypochlorous Acid
What is NaOCI?
Sodium Hypochlorite (bleach)
An increase in the heterotrophic plate count indicates?
Nitrification
What do the initials MPN mean?
Most Probable Number
What bacteria break down ammonia nitrogen to nitrites?
Nitrosomonas
Which bacteria break down nitrites to nitrates?
Nitrobacter
Which are the ideal conditions for nitrification to take place?
A dark environment, temperature between 25-30°C, a pH of 7.5-8.5, and free ammonia available
What is used to detect a chlorine leak?
Ammonia
What is used to detect a sulfur dioxide leak?
Ammonia
What is used to detect an ammonia leak?
Hydrochloric acid
If your plant is pre-chlorinating and you find that you are exceeding the MCL for THMS, what should you do?
Stop pre-chlorinating
Naturally occurring volatile organic compounds react with chlorine and form what cancer causing compound?
THMS
A pure chemical substance that is used to make new products or is used in chemical tests to measure, detect, or analyze other substances is called?
A reagent
The concentration of chlorine present in water after the chlorine demand has been satisfied is called?
Residual
What is this formula used to detect? Demand + Residual =?
Dosage
The Dosage is 5 ppm and the residual is 3 ppm. What is the demand?
2 ppm
What do you call the process of adding a chemical reagent in small increments until completion of a reaction, as signaled by the end point?
Titration
What do you call the cloudy appearance of water caused by the presence of suspended and colloidal matter?
Turbidity
Why are water plant operators concerned with turbidity?
Turbidity interferes with disinfection
What is the MCL for turbidity?
0.5 Nephelometric units
Name four bacteria found in contaminated water?
Typhoid, Cholera, Dysentery, and Salmonella
Name two parasites that are found in contaminated water?
Cryptosporidium and Giardia lamblia
What determines the number of coliform samples that a water system has to take?
Population served
What is the MCL for coliform?

If a sample tests positive for coliform what actions should be taken?
Retest at the site within 24 hour notification of the positive test and sample one site upstream and downstream from the positive site.
If a water system samples 40 or more sites for coliform, how many positive samples are allowed?
2 or 5%
If a water system samples 39 or fewer sites for coliform, how many positive samples are allowed?
1
What are the optimum conditions for disinfection?
High Cl2 concentration, long contact time, low pH, and low turbidity
Why is turbidity of the water important?
High turbidity interferes with disinfection and coagulation
The Surface Water Treatment Rule (SWTR) requires what minimum level of water treatment?
Disinfection and Filtration
Besides chlorination and ammoniation, what other processes reduce pathogens in the water?
Coagulation, Filtration, and Sedimentation
Ultraviolet rays are used to disinfect water. What limits the UV rays efficiency?
No residual; also, if a pathogen is caught between two particles, the rays have no effect on the pathogen.
What color is chlorine gas?
Greenish-yellow
Chlorine cylinders are filled to what capacity?
85% to allow for the expansion of the liquid into the gaseous state
How many parts per million of chlorine is needed to oxidize one ppm of H2S to elemental sulfur?
2.08 mg/L
How many parts per million of chlorine is needed to oxidize one ppm of H₂S to sulfates?
8.32 mg/L
If sulfur dioxide comes into contact with a person's mucous membrane, what can happen?
The formation of sulfuric acid (H₂SO₄)

What does this chemical reaction indicate?
Oxidation of H₂S by chlorine to elemental sulfur

What does this chemical reaction indicate?
Oxidation of H₂S by chlorine to sulfates or sulfuric acid (H₂SO₄)

In the last 4 questions, what do you call the oxidation process that took place?
Sub-residual chlorination
In the normal pH range of drinking water, what is the usual form of chlorine?
Monochloramines
When you add ammonia to chlorine you form?
Chloramines
When chlorine is added to water what is the usual first reaction?
Chlorine is used up (destroyed) by reducing compounds (viruses, bacteria, solids, parasites, etc)
After the reduction of the chlorine dosage, what reaction takes place?
Chlororganics and chloramines are formed - residual is present
What is the next reaction in the chlorination chain?
Residual is reduced-chlororganics and chloramines destroyed
After the reaction in question 85, what takes place?
Question 85:
What is the next reaction in the chlorination chain?
Breakpoint chlorination
What causes the swimming pool taste and odor in water?
Low chlorine residual - plant did not use breakpoint chlorination
What is the best residual for disinfection?
Free available chlorine
At water pH levels of 4.0 or lower, what form will chlorine take?
Trichloramine
Above pH of 7.5 chlorine is found as?
Monochloramines
Dichloramines and monochloramines exist together at what pH range?
5.5-7.5
Dichloramines and trichloramines are associated with what water complaint?
Tastes and odors
If chlorine is used to treat an odor caused by phenols (benzene), what happens?
The odor and taste are intensified
Customers are complaining of a sweet, aromatic, medicinal taste in the water. What is the likely cause?
Phenols
What is the best method to remove tastes and odors caused by phenols?
GAC
To avoid THM formation, what options are available to the WTP?
Switch disinfectants, remove the precursors, or form THMs and remove them after they are formed.