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Chemistry 121 Lab Final Test Review

front 1

what is the chemical name for baking soda?

back 1

Sodium-hydrogen-carbonate

front 2

what type of chemical is baking soda?

back 2

base

front 3

what is the chemical name for vinegar?

back 3

[acetic-acid]

front 4

What type of chemical is vinegar?

back 4

acid

front 5

a neutralization reaction occurs when...

back 5

an acid reacts with a base to produce water, salt, and sometimes gas.

front 6

we can determine the percent yield of a reaction by

back 6

dividing the actual yield by the theoretical yield and multiplying by 100

front 7

explain what it means when we say the mole ratio of vinegar to baking soda is 1.5:1

back 7

its means that the solution will contain 1.5 moles of vinegar and 1 mole of baking soda. there are more moles of vinegar and baking soda is the limiting reactant

front 8

explain what is means when we say that the mole ratio of vinegar to baking soda is 1:1.5

back 8

it means that the solution will contain one mole of vinegar and 1.5 moles of baking soda. there are more moles of baking soda and vinegar is the limiting reagent

front 9

if you react 25.25g of Na2CO3 with 50.0mL of 6.0M HCl, answer the following questions. (molar mass of Na2CO3 = 106.00 g/mol & molar mass of NaCl = 58.45 g/mol)
a.) write a balanced equation
b.) what type of reaction is this?
c.) How many moles of Na2CO3 do you have?
d.) How many moles of HCl do you have?
e.) how many moles of HCl do you need to completely react with 25.25 g of Na2CO3?
f.) What is the limiting reagent? What reagent is in excess?

back 9

a.) Na2CO3 + 2HCl yields 2NaCl + H2O + CO2
b.) neutralization reaction
c.) 0.2382 mol Na2CO3
d.) 0.30 mol HCl
e.) 0.4764 mol HCl
f.) limiting = HCl; excess = Na2CO3

front 10

1.75g of Ag2O is produced when 3.50 g of Ag reacts with excess O2. What is the percent yield?

4Ag(s) + O2(g) yields 2Ag2O2(s)

back 10

46.54%

front 11

What is oxidation?

back 11

the loss of electrons

front 12

What is reduction?

back 12

the gain of electrons

front 13

The oxidation number of an atom in a molecule or an ion is defined as...

back 13

the charge an atom has or appears to have as determined by the oxidation-reduction rules

front 14

An oxidation number can also be called...

back 14

an oxidation state

front 15

The best way to recognize an oxidation-reduction reaction is...

back 15

to see if the oxidation number changes as a result of the chemical reaction

front 16

What is the oxidation number of Mg(s)?

back 16

0

front 17

What is the oxidation number of H2(g)?

back 17

0

front 18

The algebraic sum of the oxidation numbers for the atoms of a neutral compound must be...

back 18

0

front 19

In a polyatomic ion, the sum of the oxidation number must be equal to...

back 19

the ion charge

front 20

What is the oxidation number of C in CO?

back 20

+2

front 21

What is the oxidation number of C in CO3 2-?

back 21

+4

front 22

What is the oxidation state of fluorine when combined with another element?

back 22

-1

front 23

The compound Ca(NO3)2 has ______ calcium atom, _______ nitrogen atoms, and ________ oxygen atoms.

back 23

1 calcium, 2 nitrogen, & 6 oxygen

front 24

In the compound Ca(NO3)2 for each mole of calcium ions there are ______ moles of nitrate ions and the mole ratio of calcium to nitrate ions is _______.

back 24

2 moles
1:2 ratio

front 25

What is a hydrate?

back 25

a compound that has water molecules loosely attached that can be removed by heating.

front 26

When the aluminum wire was placed in the solution of the copper ions, what was oxidized?

back 26

Al (s)

front 27

When the aluminum wire was placed in the solution of copper ions, what was reduced?

back 27

Cu 2+ (aq)

front 28

When the aluminum wire was placed in the solution of copper ions, what was the oxidizing agent?

back 28

Cu 2+ (aq)

front 29

When the aluminum wire was placed in the solution of copper ions, what was the reducing agent?

back 29

Al (s)

front 30

Why was an analytical balance used in the aluminum wire experiment?

back 30

because it is more accurate and can generate more sigfigs than the top loading balance

front 31

How was the top loading balance used in the aluminum wire experiment?

back 31

it was used to place slightly more than 1 gram of the unknown hydrate into the crucible

front 32

Why was the Buchner funnel used in the aluminum wire experiment?

back 32

it was used to quickly filter the copper out of the solution that was made

front 33

what is ethanol?

back 33

ethyl alcohol

front 34

why was ethanol added to the copper during filtering?

back 34

because it helps to dry the filter paper out because it has a lower boiling point than water

front 35

What is the entire name of 6M HCl

back 35

6 molar of hydrochloric acid

front 36

How did the temperature of the solution change when the wire was added?

back 36

temp. increased

front 37

Thermodynamically what type of reaction does an increase in temperature indicate?

back 37

exothermic reaction

front 38

Titration involves

back 38

the measurement of the exact volume of a solution of known concentration that is required to react with a measured amount of an unknown substance or solution

front 39

What is a standard solution?

back 39

a solution of known concentration

front 40

How is a primary solution made?

back 40

from a solid substance by accurately weighing the solid to four or more significant figures on the analytical balance. then the solid is added to a volumetric flask and diluted with distilled water to get a solution of known molarity.

front 41

A primary solution is made from a liquid by...

back 41

using a volumetric pipet to measure precise amounts of the liquid and then diluting in a volumetric flask

front 42

Because NaOH absorbs carbon] [dioxide and water from the air, it cannot be weighed accurately. Therefore, it cannot...

back 42

be a primary standard

front 43

After it has been standardized, the exact molarity of the NaOH is known & it can be...

back 43

used to standardize an unknown acid solution

front 44

Potassium hydrogen phthalate

back 44

a primary standard that can be used to standardize NaOH solutions

front 45

How many moles are needed to titrate one mole of KHC8H4O4?

back 45

one

front 46

Which acid-base indicator will be used in the experiment?

back 46

phenolphthalein

front 47

What is the color change in the acid-base reaction?

back 47

colorless to pink

front 48

We end the titration when...

back 48

one drop of the titrant causes the indicator to change color & the color stays for 30 seconds

front 49

The indicator color change indicates...

back 49

the end point of the titration and tells us the reaction is complete.

front 50

Know how to standardize HCl

back 50

pg. 83

front 51

Why wasn't it necessary to dry the Erlenmeyer flasks between samples in the standardization of HCl experiment?

back 51

you do not have to dry the flask because you are measuring a definite amount of acid into the flask for each trial & your calculations are based on the exact quantity of acid being added to the flask from the syringe. Therefore, the flask can contain distilled water or distilled water can be added without affecting the experiment

front 52

What mass of KHC8H4O4 would be neutralized by 25.25mL of 0.1034 M NaOH?

back 52

0.5332 g KHC8H4O4

front 53

How many mL of 0.1022 M NaOH are needed to neutralize 5.00 mL of a 0.1152M HCl solution?

back 53

5.64mL NaOH

front 54

Heat is...

back 54

a form of energy called thermal energy which can pass from an object at high temperature to an object at a lower temperature.

front 55

A calorimeter is...

back 55

a/an insulated container made so that no heat is lost from the container during the experiment

front 56

Styrofoam cups are used in this experiment because...

back 56

they are good insulators and relatively inexpensive

front 57

q H2O means...

back 57

the change in temperature of the water

front 58

C H2O means...

back 58

the specific heat of water

front 59

m H2O means...

back 59

the mass of water

front 60

delta t means....

back 60

the quantity of the heat of the water

front 61

Specific heat is...

back 61

the amount of heat required to raise the temperature of 1 gram of a substance by 1 degree Celsius

front 62

amounts of heat are measured in either...

back 62

[joules] or [calories].

front 63

the specific heat of water is...

back 63

4.18 joules/g(degrees celsius)

front 64

the boiling point is...

back 64

when the liquid molecules get enough energy from the added heat that they form vapor

front 65

Liquid boils when...

back 65

the vapor pressure = the atmospheric pressure

front 66

what is inside of the bubbles of a boiling liquid?

back 66

the gaseous liquid that is boiling

front 67

since atmospheric pressure decreases with increasing elevation, the water has a ....

back 67

lower boiling point at higher elevations

front 68

explain why the temperature of boiling water can be different on different days even if the elevation is the same

back 68

Air pressure changes when different weather fronts move through an area. The fronts cause changes in air pressures (highs and lows). Therefore, the temperature of boiling water can be different on different days even if the elevation is the same

front 69

enthalpy is...

back 69

the heat flow of reactions at constant pressure

front 70

if the temperature of the water in the calorimeter increases, then...

back 70

heat has been given off by the reaction mixture

front 71

If heat is given off by the reaction, then the reaction is _________. Therefore q H2O is ________ & enthalpy is _________.

back 71

exothermic, positive, & negative

front 72

Using what you learned about specific heat in lab, explain why an empty metal pan on a stove heats much faster than the same pan filled with water.

back 72

an empty metal pan on the stove heats much faster then the same pan filled with water because the metal pan has a much lower specific heat compared to water so it takes less time to heat.

front 73

Explain why your car overheats if your fan belt breaks

back 73

if your fan belt breaks there is no more air flowing through to cool the liquid that is absorbing the heat from the engine of the car.

front 74

explain why your car overheats if your radiator has a hole in it

back 74

your car would overheat if your radiator had a hole in it because all of the water would run out of the radiator so there would be no water flowing through the engine to absorb the heat, thus the car would overheat

front 75

delta t =

back 75

a change in temp.

front 76

how is delta t calculated?

back 76

by subtracting the final temp. minus that initial temp.

front 77

what is the chemical name of CaCl2?

back 77

calcium chloride

front 78

Why is CaCl2 often used in the winter to melt ice?

back 78

because when it is mixed with water (ice) the reaction is exothermic, thus the ice is melted & less dangerous

front 79

Charles Law states that....

back 79

at constant pressure the volume of a given gas is directly proportional to its Kelvin temperature

front 80

The objective of this experiment is to verify Charles Law by finding ...

back 80

the volume occupied by a gas at 2 different temperatures.

front 81

Charles law is verified if...

back 81

the volume-to-temperature ratios are close to the same number

front 82

Boyle's Law states that....

back 82

the volume of a fixed amount of gas at a constant temperature is inversely proportional to the pressure exerted on the gas

front 83

We will verify Boyle's Law by...

back 83

using a syringe that has a trapped column of gas and apply weights to increase pressure

front 84

Avogadro's Law states that...

back 84

the volume of a gas at constant temperature and pressure is directly proportional to the quantity of the gas

front 85

As you put more moles of air into a balloon the volume...

back 85

increases

front 86

Amonton's Law states...

back 86

at a constant volume and quantity, the Kelvin temperature and pressure of a gas are directly proportional

front 87

the combination of all the gas laws is the...

back 87

Ideal gas law

front 88

the equation of the Ideal gas law is

back 88

PV = nRT

front 89

STP

back 89

standard temperature and pressure

front 90

STP is defined as...

back 90

0C and 1 atm.

front 91

Molar volume of an ideal gas at STP is

back 91

22.4 L

front 92

Two 125mL _________ flasks will be used in the Charle's Law experiment

back 92

Erlenmeyer

front 93

What 2 types of clamps will be used in the Charles Law experiment?

back 93

Utility and screw clamps.

front 94

Closing the ______ clamp could cause the flask to _____ as the air expands

back 94

screw ; explode

front 95

Use the ______ clamp to remove the flask from the ________ water

back 95

utility ; boiling

front 96

When the flask is submerged in the cooling bath, check to make sure the rubber tubing ______ completely and the end of the tubing stays ______ the surface of the water.

back 96

opens ; below

front 97

The volume of the water in the 250mL graduated cylinder = volume of the _________ = volume of hot ________

back 97

flask ; air

front 98

Charles Law is proved if the difference of the k value is less than _____

back 98

0.050 mL/K

front 99

The Boyle's Law apparatus that is on your table has a ______ with a trapped column of air and a piece of _______ on top which is where you will put the weights

back 99

syringe ; wood

front 100

the weights in this experiment are ________

back 100

bricks

front 101

since the bricks are too heavy to weigh on the balances in the lab, they have all been ______ and ______ for you.

back 101

numbered & weighed

front 102

The Boyle's law apparatus is not perfect because there is ________ between the ________ and the ______ of the syringe

back 102

friction between the plunger & sides

front 103

Write the equation used to calculate % yield

back 103

(actual yield / theoretical yield) X 100

front 104

The reaction represented on page 109 is exothermic because...

back 104

; the products have less energy than the reactants

front 105

Chemists often use models made of balls and sticks or straws to represent...

back 105

atoms & bonds

front 106

Models are useful in visualizing the arrangements of atoms & bonds in these structures because...

back 106

molecules & atoms cannot be seen with the human eye

front 107

The atomic theory states...

back 107

that the chemical & physical properties of a substance are determined by the distribution of valance electrons and by the arrangement of the atoms in the molecule

front 108

A lewis structure is a...

back 108

two dimensional representation of a molecule or ion that shows the atomic symbols of the elements and dots or lines to represent electrons that are either in bonds or are unshared

front 109

The first step in drawing a Lewis structure is to...

back 109

determine the number of valance electrons

front 110

Electronegativity

back 110

the ability of an atom to attract ions to itself

front 111

What is the most electronegative element?

back 111

[Fluorine

front 112

If an atom does not obey the octet rule how many valance electrons does it have?

back 112

more than 8

front 113

Using the chart on page 121, what is the molecular geometry of a substance with the general formula of AX3E?

back 113

Trigonal Pyramidal

front 114

The general rule for bond length is...

back 114

that single bonds are the longest, double bonds are shorter, and triple bonds are the shortest of the 3 types

front 115

when compounds have more than one possible Lewis structure, these structures are called...

back 115

resonance forms

front 116

formal charge of an atom is defined as...

back 116

the total number of [valance] electrons of that atom minus the number of valance electrons it [owns] in the molecule: it owns [all] its unshared valance electrons and [half] of it’s shared valance electrons.