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Biochem 35

front 1

A pancreatic enzyme deficiency prevents activation of chymotrypsinogen, proelastase, and procarboxypeptidases. Which enzyme is most likely absent?

A. Pepsin
B. Enteropeptidase
C. Trypsin
D. Aminopeptidase

back 1

C. Trypsin

front 2

Trypsin, chymotrypsin, and elastase are all endopeptidases and share which catalytic classification?

A. Metalloproteases
B. Serine proteases
C. Aspartyl proteases
D. Cysteine proteases

back 2

B. Serine proteases

front 3

A peptide is cleaved at internal peptide bonds rather than sequentially from a terminus. Which class of enzymes performs this function?

A. Exopeptidases
B. Carboxypeptidases
C. Aminopeptidases
D. Endopeptidases

back 3

D. Endopeptidases

front 4

Which one cleaves peptide bonds in which the carboxyl (carbonyl) group is provided by lysine or arginine?

A. Elastase
B. Carboxypeptidase A
C. Chymotrypsin
D. Trypsin

back 4

D. Trypsin

front 5

A researcher designs a peptide rich in phenylalanine, tyrosine, tryptophan, and leucine. Which enzyme would most strongly favor cleavage of this substrate?

A. Chymotrypsin
B. Trypsin
C. Aminopeptidase
D. Carboxypeptidase B

back 5

A. Chymotrypsin

front 6

After pancreatic endopeptidases generate oligopeptides, which enzymes remove amino acids one at a time from peptide ends?

A. Ligases
B. Isomerases
C. Exopeptidases
D. Transaminases

back 6

C. Exopeptidases

front 7

A defect in an enzyme that removes residues sequentially from the carboxyl terminus of peptides would most directly impair which enzyme group?

A. Pepsins
B. Carboxypeptidases
C. Aminopeptidases
D. Enterokinases

back 7

B. Carboxypeptidases

front 8

preferentially releases hydrophobic AA:

A. Carboxypeptidase A
B. Carboxypeptidase B
C. Carboxypeptidase C
D. Carboxypeptidase D

back 8

A. Carboxypeptidase A

front 9

preferentially releases basic AA:

A. Carboxypeptidase A
B. Carboxypeptidase B
C. Carboxypeptidase C
D. Carboxypeptidase D

back 9

B. Carboxypeptidase B

front 10

Carboxypeptidase B most preferentially releases which amino acids?

A. Leucine and valine
B. Glycine and alanine
C. Serine and threonine
D. Arginine and lysine

back 10

D. Arginine and lysine

front 11

Which statement best describes pepsinogen physiology?

A. Produced in pancreas, activated intestine
B. Produced in stomach, activated stomach
C. Produced in liver, activated duodenum
D. Produced in jejunum, activated colon

back 11

B. Produced in stomach, activated stomach

front 12

Which enzyme is located on the brush border and removes single amino acids from the amino terminus of peptides?

A. Aminopeptidase
B. Trypsin
C. Elastase
D. Cathepsin

back 12

A. Aminopeptidase

front 13

Proteins can be degraded by lysosomal enzymes called:

A. Caspases
B. Cathepsins
C. Carboxypeptidases
D. Granzymes

back 13

B. Cathepsins

front 14

An intracellular protein is marked for degradation by covalent attachment of a small peptide to lysine residues. Which molecule provides this targeting signal?

A. SUMO
B. Biotin
C. Ubiquitin
D. Carnitine

back 14

C. Ubiquitin

front 15

After polyubiquitination, a damaged cytosolic protein is most directly sent to which structure?

A. Proteasome
B. Peroxisome
C. Lysosome
D. Endosome

back 15

A. Proteasome

front 16

A regulatory protein contains regions rich in proline, glutamate, serine, and threonine. What is the most likely effect of this sequence motif?

A. Enhanced secretion
B. Mitochondrial import
C. Longer half-life
D. Shorter half-life

back 16

D. Shorter half-life

front 17

Amino acids enter intestinal epithelial cells from the lumen primarily through which mechanism?

A. Primary active Ca2+ pump
B. Na+-dependent cotransport
C. Cl− antiport
D. Simple diffusion only

back 17

B. Na+-dependent cotransport

front 18

Once concentrated within intestinal epithelial cells, amino acids typically leave across the basolateral membrane by:

A. Facilitated transport
B. Na+/K+ ATPase
C. Proton symport
D. Endocytic vesicles

back 18

A. Facilitated transport

front 19

In a prolonged fasting state, which statement best describes amino acid handling by intestinal epithelial cells?
A. Minimally use amino acids for energy
B. Rely mainly on luminal amino acids
C. Release amino acids into the lumen
D. Take up blood amino acids for fuel

back 19

D. Take up blood amino acids for fuel

front 20

Which kinase has an important regulatory role in autophagy?

A. AMPK
B. PKA
C. Akt
D. mTOR

back 20

D. mTOR

front 21

In proteasomal degradation, what is used both to unfold the tagged protein and to push the protein into the core of the cylinder?

back 21

ATP hydrolysis

front 22

Digestive proteases are generally synthesized in inactive precursor forms best termed:

A. Isoenzymes
B. Zymogens
C. Apoenzymes
D. Holoproteins

back 22

B. Zymogens

front 23

What cells secrete hydrochloric acid (HCL)?

back 23

parietal cells

front 24

What cells secrete pepsinogen?

back 24

Chief cells

front 25

A child in a famine-stricken region has generalized edema, muscle wasting, and preserved caloric intake from starches. Which diagnosis best fits?

A. Kwashiorkor
B. Marasmus
C. Pellagra
D. Scurvy

back 25

A. Kwashiorkor

front 26

The edema of kwashiorkor is most directly caused by decreased levels of which plasma protein?

A. Fibrinogen
B. Transferrin
C. Albumin
D. Ceruloplasmin

back 26

C. Albumin

front 27

A toddler with protein deficiency appears swollen rather than cachectic. Which finding most specifically explains the apparent “plump” appearance?

A. Hepatic glycogen accumulation
B. Mesenteric inflammation
C. Edema with distended abdomen
D. Increased subcutaneous adipose

back 27

C. Edema with distended abdomen

front 28

Why must pancreatic zymogens be activated within a short span after trypsin appears?

A. Active enzymes digest one another
B. Bile salts rapidly inactivate them
C. Luminal pH soon denatures them
D. Brush-border enzymes remove them

back 28

A. Active enzymes digest one another

front 29

A congenital defect prevents conversion of trypsinogen to trypsin at the intestinal surface. Which enzyme is deficient?

A. Aminopeptidase
B. Carboxypeptidase B
C. Pepsin
D. Enteropeptidase

back 29

D. Enteropeptidase

front 30

_____ first activates a small amount of trypsinogen into trypsin, which then triggers a rapid cascade by cleaving all other pancreatic zymogens into their _____ forms.

This immediate activation ensures that these potent proteases begin digesting dietary proteins simultaneously before they can undergo autolysis or autodigestion.

back 30

Enteropeptidase

active

front 31

Enteropeptidase is secreted by which cells?

A. Pancreatic acinar cells
B. Small-intestinal brush-border cells
C. Gastric chief cells
D. Duodenal goblet cells

back 31

B. Small-intestinal brush-border cells

front 32

Failure of trypsin generation would most directly impair activation of all except which enzyme?

A. Chymotrypsin
B. Elastase
C. Carboxypeptidases
D. Pepsin

back 32

D. Pepsin

front 33

A child with cystic fibrosis develops protein, fat, and carbohydrate maldigestion from pancreatic insufficiency. The primary defect initially causes inspissation of which secretions?

A. Endocrine pancreatic secretions
B. Biliary canalicular secretions
C. Pancreatic exocrine secretions
D. Gastric chief-cell secretions

back 33

C. Pancreatic exocrine secretions

front 34

In cystic fibrosis, failure of pancreatic enzymes to reach the intestinal lumen is caused primarily by:

A. Zymogen overactivation
B. Ductal obstruction
C. Brush-border atrophy
D. Decreased enteropeptidase

back 34

B. Ductal obstruction

front 35

The pancreas synthesizes a secretory trypsin inhibitor primarily to prevent:

A. Intrapancreatic zymogen activation
B. Pepsin-mediated mucosal injury
C. Renal amino acid wasting
D. Lysosomal proteolysis

back 35

A. Intrapancreatic zymogen activation

front 36

Loss of pancreatic trypsin inhibitor would most likely predispose to which condition?

A. Cystinuria
B. Hartnup disease
C. Kwashiorkor
D. Pancreatitis

back 36

D. Pancreatitis

front 37

Hartnup disease is caused by defective transport of which class of amino acids?

A. Basic amino acids
B. Neutral amino acids
C. Acidic amino acids
D. Sulfur-containing amino acids

back 37

B. Neutral amino acids

front 38

Hartnup disease affects transport across which epithelial sites?

A. Hepatic and alveolar
B. Gastric and colonic
C. Intestinal and renal
D. Biliary and pancreatic

back 38

C. Intestinal and renal

front 39

In both Hartnup disease and cystinuria, impaired tubular handling causes what urinary change?

A. Increased urinary amino acids
B. Decreased urinary amino acids
C. Increased urinary glucose
D. Decreased urinary ketones

back 39

A. Increased urinary amino acids

front 40

Excess amino acid carbon skeletons are primarily converted into:

A. Cholesterol and ketones
B. Lactate and pyruvate
C. Purines and porphyrins
D. Glycogen and triacylglycerols

back 40

D. Glycogen and triacylglycerols

front 41

A young adult with recurrent nephrolithiasis has stones composed of a poorly soluble amino acid. Which substance is the culprit in cystinuria?

A. Tyrosine
B. Tryptophan
C. Cystine
D. Taurine

back 41

C. Cystine

front 42

A patient with cystinuria presents with severe flank pain radiating to the groin and gross hematuria. Which complication most likely explains this presentation?

A. Papillary necrosis
B. Bladder rupture
C. Glomerulonephritis
D. Ureteral stone obstruction

back 42

D. Ureteral stone obstruction

front 43

A misfolded cytosolic protein is targeted for proteasomal degradation after a small peptide is covalently attached to the ε-amino group of which residue?

A. Serine
B. Lysine
C. Arginine
D. Histidine

back 43

B. Lysine

front 44

Proteins rich in proline, glutamate, serine, and threonine are typically degraded by which pathway?

A. Lysosomal cathepsin pathway
B. Calpain-mediated proteolysis
C. Ubiquitin–proteasome system
D. Caspase-dependent cleavage

back 44

C. Ubiquitin–proteasome system

front 45

The γ-glutamyl cycle is required for synthesis of which antioxidant compound?

A. Taurine
B. Bilirubin
C. Glutathione
D. Uric acid

back 45

C. Glutathione

front 46

Glutathione is protection against:

A. Thermal injury
B. Oxidative damage
C. Osmotic stress
D. Calcium overload

back 46

B. Oxidative damage

front 47

Which protease is active within the stomach lumen?

A. Trypsin
B. Elastase
C. Pepsin
D. Aminopeptidase

back 47

C. Pepsin

front 48

Which set contains only pancreatic proteases?

A. Pepsin, trypsin, aminopeptidase
B. Trypsin, chymotrypsin, elastase
C. Pepsin, elastase, carboxypeptidase
D. Aminopeptidase, trypsin, pepsin

back 48

B. Trypsin, chymotrypsin, elastase

front 49

Which enzyme is located on the intestinal brush border?

A. Chymotrypsin
B. Elastase
C. Carboxypeptidase A
D. Aminopeptidase

back 49

D. Aminopeptidase

front 50

Cystinuria results from defective renal reabsorption of which amino acids?

A. Cysteine, arginine, lysine
B. Glycine, alanine, serine
C. Aspartate, glutamate, taurine
D. Phenylalanine, tyrosine, tryptophan

back 50

A. Cysteine, arginine, lysine

front 51

The most serious complication of cystinuria results from the poor solubility of:

A. Cysteine
B. Methionine
C. Homocysteine
D. Cystine

back 51

D. Cystine

front 52

Neutrophil-derived elastase is normally inhibited by which molecule?

A. α-1-antitrypsin
B. Transferrin
C. Ceruloplasmin
D. Hemopexin

back 52

A. α-1-antitrypsin

front 53

Alpha-1 antitrypsin deficiency (AATD) is a genetic condition causing low levels of the protective protein AAT, leading to:

A. Pulmonary fibrosis
B. Emphysema
C. Bronchiectasis
D. Pulmonary edema

back 53

B. Emphysema

front 54

The lung injury in α-1-antitrypsin deficiency is primarily due to:

A. Autoimmune alveolitis
B. Infectious necrosis
C. Proteolytic tissue destruction
D. Surfactant overproduction

back 54

C. Proteolytic tissue destruction

front 55

Pepsinogen becomes pepsin when gastric acidity increases because:

A. HCl directly hydrolyzes proteins
B. Low pH activates pepsinogen
C. Gastrin cleaves pepsinogen
D. Bicarbonate exposes active site

back 55

B. Low pH activates pepsinogen

front 56

Cystinuria is most directly caused by which underlying abnormality?

A. Defective glomerular filtration barrier
B. Mutated tubular amino acid transporter
C. Excess hepatic cystine synthesis
D. Deficient lysosomal cysteine export

back 56

B. Mutated tubular amino acid transporter

front 57

Which statement best describes pepsin’s enzymatic action?

A. Carboxyl-terminal exopeptidase
B. Amino-terminal exopeptidase
C. Endopeptidase in stomach
D. Cytosolic ubiquitin ligase

back 57

C. Endopeptidase in stomach

front 58

Which group contains only endopeptidases?

A. Pepsin, trypsin, elastase
B. Aminopeptidase, pepsin, trypsin
C. Carboxypeptidase, elastase, pepsin
D. Aminopeptidase, carboxypeptidase, pepsin

back 58

A. Pepsin, trypsin, elastase

front 59

Which pair contains only exopeptidases?

A. Pepsin and trypsin
B. Chymotrypsin and elastase
C. Trypsin and aminopeptidase
D. Carboxypeptidase and aminopeptidase

back 59

D. Carboxypeptidase and aminopeptidase

front 60

Which event is the key initiating step that leads to activation of the major pancreatic zymogens?

A. Pepsinogen cleavage by HCl
B. Enteropeptidase activates trypsinogen
C. Aminopeptidase activates pepsin
D. Elastase activates trypsinogen

back 60

B. Enteropeptidase activates trypsinogen

front 61

During acute inflammation, elastase released from which cell type can contribute to tissue injury if not properly inhibited?

A. Eosinophil
B. Neutrophil
C. Macrophage
D. Fibroblast

back 61

B. Neutrophil

front 62

Exopeptidases are best defined as enzymes that:

A. Cleave internal peptide bonds
B. Remove one terminal residue
C. Hydrolyze disulfide bonds
D. Deaminate free amino acids

back 62

B. Remove one terminal residue

front 63

Which kinase directly integrates nutrient and growth factor signals to inhibit autophagy when active?
A. AMPK
B. mTOR
C. Akt
D. GSK3β

back 63

B. mTOR

front 64

During energy deprivation, which kinase is activated to initiate autophagy via mTOR inhibition?
A. Akt
B. JAK2
C. AMPK
D. ERK1/2

back 64

C. AMPK

front 65

In the low-energy autophagy pathway, what is the direct effect of AMPK on the TSC1/TSC2 complex?
A. Phosphorylates and activates TSC1/TSC2
B. Dephosphorylates and inactivates TSC1/TSC2
C. Induces degradation of TSC1/TSC2
D. Prevents transcription of TSC1/TSC2

back 65

B. Dephosphorylates and inactivates TSC1/TSC2

front 66

Under low-energy conditions, with inactive Rheb and inhibited mTOR, what happens to autophagy?
A. mTOR activated, autophagy blocked
B. mTOR unchanged, autophagy unchanged
C. mTOR inhibited, autophagy blocked
D. mTOR inhibited, autophagy proceeds

back 66

D. mTOR inhibited, autophagy proceeds

front 67

In the presence of insulin or growth factors, which kinase is activated upstream of mTOR to oppose autophagy?
A. AMPK
B. PKC
C. JNK
D. Akt

back 67

D. Akt

front 68

Under insulin signaling with active Rheb-GTP, what is the net effect of mTOR on cell processes?
A. Stimulates autophagy and protein synthesis
B. Stimulates autophagy and inhibits protein synthesis
C. Inhibits autophagy and stimulates protein synthesis
D. Inhibits both autophagy and protein synthesis

back 68

C. Inhibits autophagy and stimulates protein synthesis

front 69

A patient presents with diarrhea, dermatitis, and dementia. Pellagra is suspected. This syndrome most commonly results from deficiency of:
A. Niacin or dietary tryptophan
B. Riboflavin or dietary tyrosine
C. Biotin or dietary cysteine
D. Folate or dietary glycine

back 69

A. Niacin or dietary tryptophan

front 70

In cystinuria, the abnormal transport protein normally reabsorbs amino acids from which location?

A. Blood into glomerulus
B. Kidney lumen into tubular cells
C. Tubular cells into blood
D. Liver into bile canaliculi

back 70

B. Kidney lumen into tubular cells

front 71

Which enzyme is both a pancreatic protease and an exopeptidase?

A. Chymotrypsin
B. Pepsin
C. Carboxypeptidase
D. Aminopeptidase

back 71

C. Carboxypeptidase

front 72

Which metabolic condition most directly activates AMPK in the autophagy pathway described?

A. High ATP state
B. High AMP state
C. High insulin state
D. High Rheb state

back 72

B. High AMP state

front 73

In the fed state, activation of mTOR has which additional major effect besides inhibiting autophagy?

A. Blocks peptide absorption
B. Stimulates protein synthesis
C. Activates ubiquitination
D. Suppresses Akt signaling

back 73

B. Stimulates protein synthesis

front 74

Which of the following proteases is primarily responsible for the execution of programmed cell death (apoptosis)?

A. Matrix metalloproteinases

B. Caspases

C. Calpains

D. Serine proteases

back 74

B. Caspases

front 75

Which group of proteases plays a major role in physiological processes such as digestion and blood clotting?

A. Caspases

B. Calpains

C. Serine proteases

D. Matrix metalloproteinases

back 75

C. Serine proteases

front 76

The remodeling of extracellular matrix components is a function primarily attributed to which of the following?

A. Proteasomes

B. Matrix metalloproteinases

C. Serine proteases

D. Caspases

back 76

B. Matrix metalloproteinases

front 77

Which of these cysteine proteases is described as having "many different cellular roles" that are strictly dependent on calcium levels?

A. Serine proteases

B. Caspases

C. Calpains

D. Proteasomes

back 77

C. Calpains

front 78

A segment of dietary protein consists mainly of alanine, glycine, and serine. Which enzyme preferentially cleaves peptide bonds whose carboxyl group is contributed by these small side chains?
A. Pepsin
B. Trypsin
C. Chymotrypsin
D. Elastase

back 78

D. Elastase

front 79

Which statement best describes the cap complexes regulating the ubiquitin–proteasome system?
A. Two calcium-dependent caps bind substrates
B. Caps detach ubiquitin using lysosomal enzymes
C. Caps inhibit ATP use during degradation
D. Four ATP-dependent caps recognize ubiquitin

back 79

D. Four ATP-dependent caps recognize ubiquitin

front 80

In both Hartnup disease and cystinuria, how are the affected amino acids handled?
A. Tubular reabsorption increased, urinary levels decreased
B. Tubular secretion increased, reabsorption unchanged
C. Tubular reabsorption decreased, urinary levels increased
D. No filtration, so none appear in urine

back 80

C. Tubular reabsorption decreased, urinary levels increased