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Lecture 11: Carbohydrates

front 1

D-monosaccharides penultimate carbon has its OH on the _______. While L-monosaccharides penultimate carbon has its OH on the _________

back 1

D-right , L-left

front 2

What are enantiomers?

back 2

Stereoisomers that are mirror images ( D and L configuration )

front 3

What are diastereomers?

back 3

Stereoisomers that are not mirror images

front 4

What are epimers?

back 4

Diastereomers that only differ by 1 carbon

front 5

The alpha OH is ______ the ring. The beta OH is ______ the ring

back 5

Alpha=> ants => down (trans)

Beta => birds => up (cis)

front 6

What are the steps to drawing a Haworth structure from a Fischer projection?

back 6

1) Number the carbons

2) Turn the backbone 90 degrees sidewways. (Right= down)(Left=up)

3) Cyclize it by connecting the O to the C=O (Turn the 4th carbon H and OH gets switched)

4) Pick any anomer

front 7

What reduces an aldehyde to alcohol (alditol)?

back 7

NaBH4

front 8

What is Sorbitol?

back 8

It is in foods like prunes and cherries and acts like a laxative because it absorbs a lot of water.

front 9

What is Xylitol?

back 9

In gum. Helps oral biome of those who chew it and also transfers to the fetus if a pregnant mother chews it

front 10

What is the Maillard Reaction?

back 10

Carmelization. Sugar is oxidized and protein is reduced by heat

front 11

Reducing Sugars

back 11

Aldehyde oxidized to carboylic acid (1/3 alpha anomer)(2/3 beta anomer)

front 12

What happens when blood sugar is high for a while?

back 12

Allows glucose to enter red blood cells. Hemoglobin gets glycosylated (HbA1c or A1c). Lessens oxygen delivery increasing the risk of cardiovascular disease, renal (kidney) failure or damage to small blood vessels and nerves.

front 13

What is formed by the transfer of a phosphate group from ATP

back 13

Phosphoester

front 14

What does you call two or more monosaccharides connected by an O-glycosidic bond?

back 14

Oligosaccharides which is formed by condensation

front 15

5-8% of this sugar is in human milk, 4-5% in cow's milk.

D-galactose + D-glucose joined by a Beta (1->4) glycosidic bond

And is cleaved by ________

back 15

Lactose and is cleaved by lactase

front 16

This sugar is D-glucose + D-glucose joined by an alpha (1->4) glycosidic bond

Is cleaved by _________

back 16

Maltose and is cleaved by Maltase

front 17

This table sugar from sugar cane and sugar beets are made by D-glucose + D- fructose joined by an alpha (1->2) glycosidic bond

This is cleaved by ________

back 17

Sucrose and is cleaved by Sucrase

front 18

What are some examples of disaccharides?

back 18

Lactose, Maltose, and Sucrose

front 19

What are some examples of polysaccharides

back 19

Cellulose, Starch, and Glycogen