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Quiz 4 -

front 1

Which of the following would exhibit hydrogen bonding in a pure substance?

A) HCl

B) CH₃CH₃

C) CF₂H₂

D) CH₃CH₂OH

E) CH₃OCH₃

back 1

D) CH₃CH₂OH

front 2

Which of the following represents the intermolecular forces present in CO₂?

A) dispersion only

B) dipole-dipole only

C) hydrogen bonding only

D) dispersion and dipole-dipole

E) dispersion and hydrogen bonding

back 2

A) dispersion only

front 3

What intermolecular forces are present between two molecules of CH₃CF₃?

A) dispersion only

B) dispersion and dipole-dipole

C) dispersion, dipole-dipole, and hydrogen bonding

D) dispersion and hydrogen bonding+

back 3

B) dispersion and dipole-dipole

front 4

What intermolecular forces are present between two molecules of CH₃OCH₂CH₃?

A) dispersion only

B) dipole-dipole only

C) dispersion and dipole-dipole

D) dispersion and hydrogen bonding

E) dipole-dipole and hydrogen bonding

back 4

C) dispersion and dipole-dipole

front 5

Ammonia and hydrogen fluoride both have unusually high boiling points due to _____

A) dispersion forces.

B) dipole-dipole interactions.

C) hydrogen bonding.

D) ion-dipole interactions.

E) low molar masses.

back 5

C) hydrogen bonding.

front 6

Which of the following would you expect to have the highest boiling point?

A) H₂

B) NH₃

C) N₂

D) CH₄

back 6

B) NH₃

front 7

Convert 287 kPa to atm

back 7

2.83 atm.

front 8

How many atm is 23.4 psi?

back 8

1.59 atm

front 9

How many mmHg are in 89.6 kPa?

back 9

672 mmHg

front 10

How many torr are in 42.6 psi?

back 10

2.20 × 10³ torr

front 11

Which one of the following is NOT a statement of the Kinetic Molecular Theory?

A) Gas particles will be attracted to one another.

B) The volume available to the gas particles is equal to the volume of the container.

C) The measured pressure is from collisions of the gas particles with the walls of the container.

D) The average kinetic energy is proportional to the temperature of the system.+

back 11

A) Gas particles will be attracted to one another.

front 12

How do you convert a Celsius temperature to Kelvin?

A) Multiply by 9/5 and then add 32

B) Subtract 273.15

C) Subtract by 32, then multiply by 5/9

D) Add 273.15

E) Celsius is always the same as Kelvin

back 12

D) Add 273.15

front 13

Which of the following temperatures is the coldest?

A) 100 K

B) 100 °C

C) 100 °F

back 13

A) 100 K

front 14

How do you convert a Fahrenheit temperature to Celsius?

A) Multiply by 9/5 and then add 32

B) Subtract 273.15

C) Subtract by 32, then multiply by 5/9

D) Add 273.15

E) Celsius is always the same as Kelvin

back 14

C) Subtract by 32, then multiply by 5/9

front 15

A thermometer reads 52.3 °C. What is the temperature in Fahrenheit?

back 15

126.14 °F

front 16

A thermometer reads 18.3 °C. What is the temperature in Kelvin?

back 16

291.5 K

front 17

A thermometer reads -111.1 °F. What is the temperature in °C?

back 17

-79.5 °C

front 18

A thermometer reads -111.1 °F. What is the temperature in Kelvin?

back 18

193.7 K

front 19

A sample of argon has a volume of 1.20 L at STP. If the temperature is increased to 22.0°C and the pressure is lowered to 0.800 atm, what will the new volume be, in L?

back 19

1.62 L

front 20

A weather balloon calibrated at 0.00 °C to have a volume of 20.0 L has what volume in L at -40.0 °C assuming pressure is held constant?

back 20

17.1 L

front 21

The gas in a 250.0 mL piston experiences a change in pressure from 1.00 atm to 2.80 atm. What is the new volume (in mL) assuming the moles of gas and temperature are held constant?

back 21

89.3 mL

front 22

A 1.20 L weather balloon on the ground has a temperature of 25.0°C and is at atmospheric pressure (1.00 atm). When it rises to an elevation where the pressure is 0.720 atm, then the new volume is 1.80 L. What is the temperature (in °C) of the air at this elevation?

back 22

49 °C

front 23

At STP, 5.00 mol of gas occupies approximately what volume in liters?

back 23

112 L

front 24

How many moles of chlorine gas at 110 °C and 28.0 atm would occupy a vessel of 15.0 L?

A) 0.0749 mol

B) 13.4 mol

C) 46.5 mol

D) 0.132 mol+

back 24

B) 13.4 mol

front 25

What temperature (in °C) did an ideal gas shift to if it was initially at -10.00 °C at 4.620 atm and 35.00 L and the pressure was changed to 8.710 atm and the volume changed to 15.00 L?-71

back 25

-60.6 °C

front 26

A sample of 2.00 mol of gas in a 10.00 L container is at 45.0 °C. What is the pressure (in atm) of the gas?

back 26

5.22 atm

front 27

Write the formula of the conjugate base of the Brønsted-Lowry acid, CH₃CH₂COOH

back 27

CH₃CH₂COO⁻

front 28

Write the formula of the conjugate base of the Brønsted-Lowry acid, HF

back 28

F⁻

front 29

Write the formula of the conjugate base of the Brønsted-Lowry acid, NH₄⁺

back 29

NH₃

front 30

Consider the reaction below. Which species is(are) the Brønsted-Lowry base(s)? HCO₃⁻ (aq) + F⁻ (aq) ⇌ CO₃²⁻ (aq) + HF (aq)

A) F⁻, HF

B) HCO₃⁻, F⁻

C) CO₃²⁻, HF

D) CO₃²⁻, F⁻+

back 30

D) CO₃²⁻, F⁻

front 31

Which of the following is a conjugate acid/base pair?

A) H₃PO₄, PO₄³⁻

B) H₂PO₄⁻, PO₄³⁻

C) HPO₄²⁻, PO₄³⁻

D) H₃PO₄, HPO₄²⁻

back 31

C) HPO₄²⁻, PO₄³⁻

front 32

Write the basic equilibrium equation for NH₃

back 32

NH₃(aq) + H₂O(l) ⇌ OH⁻(aq) + NH₄⁺(aq)

front 33

Write the acidic equilibrium equation for C₃H₇COOH.

back 33

HA(aq) + H₂O(l) ⇌ A⁻(aq) + H₃O⁺(aq)

front 34

The equation below is best described as ___________.

²³⁵₉₂U → ²³⁵₉₃Np + ⁰₋₁e

A) alpha decay.

B) beta decay.

C) gamma emission.

D) positron emission.+

back 34

B) beta decay.

front 35

Which of the following symbols represents a beta particle?

A) ⁰₊₁e

B) ⁰₋₁e

C) ⁴₂He

D) γ+

back 35

B) ⁰₋₁e

front 36

Which of the following symbols represents an alpha particle?

A) ⁰₊₁e

B) ⁰₋₁e

C) ⁴₂He

D) γ

back 36

C) ⁴₂He

front 37

What is the product of alpha emission from uranium-238?

A) ²³⁴U

B) ²³²Th

C) ²³⁴Th

D) ²³⁷Np

E) ²³¹Pa+

back 37

C) ²³⁴Th

front 38

Complete the following nuclear decay process: ²³⁵₉₂U → ⁴₂He + ___

A) ²³⁹₉₄Pu

B) ²³¹₉₄Pu

C) ²³¹₉₂U

D) ²³¹₉₀Th

E) ²³⁹₉₀Th

back 38

D) ²³¹₉₀Th

front 39

The Cs-131 nuclide has a half-life of 30 years. After 120 years, 3.0 g remain. What is the original mass of the Cs-131 sample in grams?

back 39

48 g

front 40

10 g of a radioactive substance was placed in an airtight container 50 years ago. When the container is opened, only 2.5 g remains. What is the half-life of this material?

A) 5 years

B) 25 years

C) 50 years

D) 80 years

E) 100 years

back 40

B) 25 years

front 41

One of the radioactive isotopes used in chemical and medical research is sulfur-35, which has a half-life of 87 days. How many days would it take for 0.25 g to remain of a 1.00 g sample of sulfur-35?

back 41

174 days

front 42

What species is formed by gamma ray emission of fermium-250?

A) ²⁵⁰Es

B) ²³⁰Th

C) ²⁵⁰Fm

D) ²⁵¹Fm

E) ²⁵¹Md

back 42

C) ²⁵⁰Fm

front 43

What species is produced when californium-253 undergoes alpha particle emission?

A) ²⁵²Bk

B) ²⁴⁹Cm

C) ²⁵³Es

D) ²⁵¹Cm

E) ²⁵²Es

back 43

B) ²⁴⁹Cm

front 44

Complete the following nuclear bombardment equation by filling in the nuclear symbol for the missing species.

²³⁵₉₂U + ¹₀n → ? + ¹³⁹₅₄Xe + 3 ¹₀n

A) ⁹⁴₄₈Cd

B) ⁹⁶₃₈Cm

C) ⁹⁴₃₈Pu

D) ⁹⁴₃₈Sr

E) ⁹⁶₃₈Sr

back 44

D) ⁹⁴₃₈Sr

front 45

²³⁵U undergoes fission by one neutron to produce ¹³³Sb, three neutrons, and what other nuclide?

A) ¹⁰⁰Zr

B) ¹⁰⁰Nb

C) ¹⁰¹Nb

D) ¹⁰⁰Mo

E) ¹⁰²Mo

back 45

B) ¹⁰⁰Nb

front 46

Assuming only one product forms, what nuclide is produced from the fusion reaction between ³H and ⁴He?

A) ⁷He

B) ⁷N

C) ⁷Li

D) ³N

E) ³Li

back 46

C) ⁷Li

front 47

Bombarding nuclei with neutrons is characteristic of

A) fission reactions only.

B) fusion reactions only.

C) both fission reactions and fusion reactions.

D) neither fission reactions nor fusion reactions.

back 47

A) fission reactions only.