Experiment 25: Amines (final review) INC Flashcards


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1

Compare the relative base strengths of ammonia, ethylamine, and aniline. Explain in terms of electronic effects.

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2

Write a balanced equation for the reaction of ammonia and ferric chloride.

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3

Write a balanced equation for the reaction of ethylamine and ferric chloride.

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4

Write a balanced equation for the reaction of aniline and ferric chloride.

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5

Write a balanced equation for the reaction of aniline with H2SO4.

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6

Write a balanced equation for the reaction of aniline with HCl.

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7

Why are amines often darkly colored?

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8

How can amines be purified?

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9

Explain, using appropriate equations, how primary amines react in the Hinsberg Test.

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10

Explain, using appropriate equations, how secondary amines react in the Hinsberg Test.

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11

Explain, using appropriate equations, how tertiary amines react in the Hinsberg Test.

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12

What is the equation for the reaction of aniline with acetic anhydride?

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13

What is the equation for the reaction of aniline with benzoyl chloride?

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14

Why is a base necessary in the reaction of aniline with benzoyl chloride??

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15

What is the equation for the reaction of aniline with phenyl-isothiocyanate?

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16

What characteristic IR absorbency are given by a primary amines and secondary amines?

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17

Primary, secondary, teritiary Amines

http://masterorganicchemistry.files.wordpress.com/2010/06/1-carb.jpg

18

Water Solubility

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19

Basicity

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20

Hinsberg Test

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21

Oxidation

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22

Acetyl Derivative Test

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23

Benzoyl Derivative Test

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24

Diphenylthiourea Derivative Test

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25

Nucleophillic acyl addition

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26

Nucleophillic acyl substitution

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